15. Annie Turnbo Malone, Entrepreneur

Annie Turnbo Malone is often best known for being the mentor and eventual rival of haircare and bath product mogul Madame C. J. Walker, but Malone was an incredibly successful entrepreneur in her own right. She became a millionaire in the 1920s by developing and selling door-to-door her own line of haircare products targeted to black women. Annie had a factory built to create her products and established Poro College for training new saleswomen. She was also a generous philanthropist, donating a great deal of money to black organizations and families in need.



